Abstract

A one-dimensional lattice model with non-ferroelectric boundary sites has been used to study the effect of size on the polarization-reversal process in ferroelectric films. We assume non-ferroelectric imperfections at the boundary sites which act as nuclei for the polarization reversal, and include them explicitly in the free energy. The dependences of the switching time on film thickness and on electric field strength have been obtained, and fitted with empirical formulae. The time evolution of the polarization under a step field has also been simulated, from which we can clearly see domain wall formation and motion. The polarization and current under a bipolar pulse signal are also obtained to demonstrate the different memory state responses, in which a back-switching phenomena can be observed clearly.

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