Abstract
β-NaYF4:Yb3+(25%),Ho3+(1%) microprisms with different grain sizes were synthesized by a hydrothermal method. The structure, composition and upconversion emission properties of the products were characterized by scanning electron microscopy, x-ray diffractometer, inductively coupled plasma atomic emission spectrometry and spectrophotometer. It is found that with the decrease of NaF/NH4HF2 ratios in solution, the lengths of the β-NaYF4:Yb3+(25%),Ho3+(1%) microprisms increase from ~5 to ~15μm. The enhancements in the UC emissions with the increase of grain sizes resulted from the raise of the Yb3+ concentrations in crystals. Applying these materials at the back of a-Si single junction and a-Si/a-Si tandem solar cells, currents of 2.34 and 1.02μA are obtained under 60mW (80mW/cm2) 980nm laser excitation, respectively.
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