Abstract
Abstract The single crystal polarized spectra of the Fe(H2O)6 ++ ion as the perchlorate salt have been obtained at room temperature and 10°K. The spectra are very dichroic at low temperature. The major bands show a large decrease in area upon cooling suggesting that the band intensities result from a vibronic coupling mechanism. The spectra are interpreted in terms of D3d symmetry where the C3 axis is collinear with co of the pseudohexagonal unit cell. The major features of the spectra are assigned and an analysis of the vibronic mechanism is presented.
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