The silica-doped sulfonated poly(fluorenyl ether ketone)s membrane using hydroxypropyl methyl cellulose as dispersant for high temperature proton exchange membrane fuel cells

Abstract

Abstract The sulfonated poly(fluorenyl ether ketone)s (SPFEK) membranes doped with SiO 2 and dispersed by hydroxypropyl methyl cellulose (HPMC) were prepared and investigated for polymer electrolyte membrane fuel cells (PEMFCs) used at high temperature and low relative humidity (RH). The above membrane was prepared by solution dispersion of SPFEK and SiO 2 using HPMC as dispersant. The physio-chemical properties of the hybrid membrane were studied by means of scanning electron microscope (SEM), ion-exchange capacity (IEC), proton conductivity, and single cell performance tests. The hybrid membranes dispersed by HPMC were well dispersed when compared with common organic/inorganic hybrid membranes. The hybrid membranes showed superior characteristics as a proton exchange membrane (PEM) for PEMFC application, such as high ionic exchange content (IEC) of 1.51 equiv/g, high temperature operation properties, and the satisfactory ability of anti-H 2 crossover. The single cell performances of the hybrid membranes were examined in a 5 cm 2 commercial single cell at both 80 °C and 120 °C under different relative humidity (RH) conditions. The hybrid membrane dispersed by HPMC gave the best performance of 260 mW/cm 2 under conditions of 0.4 V, 120 °C, 50% RH and ambient pressure. The results demonstrated HPMC being an efficient dispersant for the organic/inorganic hybrid membrane used for PEM fuel cell.