Abstract
Abstract It is shown that the Shuttleworth equation g=γ+∂γ/∂e is valid for the interface between a solid isotropic electrode and a liquid electrolyte in the case of an infinitesimal surface deformation only. In the equation above, g is the surface stress, γ is the interfacial tension, and e is the scalar surface strain variable (elastic surface deformation). In the general case of a finite surface strain, the interfacial tension is a function of two scalar strain variables rather than one. Under conditions of an elastic finite surface strain, the modified Shuttleworth equation is deduced for the trace of the tensor of the surface stress. The Shuttleworth equation above takes into account the existence of both scalar elastic surface strain variables.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
