Abstract

Adsorption colloid flotation has been found capable of separating ionic mercury from sea water quantitatively at levels as low as 0.02 μg l −1 with use of a cadmium sulfide collector and octadecyltrimethylammonium chloride as the surfactant. The mercury in 25 samples can be separated in 2 h. Following the separation the mercury was analyzed by flameless atomic absorption. Recovery of mercury from 0.5 l samples spiked with 0.010 μg of inorganic mercury gave sol|0.014 ± 0.002 μg/0.5 l. Black Point, Oahu near-shore sea water was found to contain mercury in the range 0.038–0.078 μg l −1 with no measurable organic mercury fraction. Sea-water samples collected at an open ocean station analyzed for total mercury revealed the highest mercury concentrations above 200 meters. Mercury concentrations in general showed a decreasing trend with increase in depth.

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