Abstract

The thin-layer chromatographic behaviour of a number of metal ions in methyl alcohol, ethyl alcohol, acetone, or dioxan—nitric acid media on silica gel—cellulose (5:2) thin-layer plates impregnated with a polysulphide polymer has been investigated. Cu(II), Bi(III), Hg(II) and Ag(I) form precipitates with the polysulphide polymer in the thin-layer and remain at or near the starting points. Thus they can be easily separated from the other metal ions (Tl(I), Pb(II), Co(II), Zn(II), Cd(II), Al(III), etc.), which move with the solvent. Mixtures of various metal ions can also be separated.

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