The selenite-capped polyoxo-4-aurate(iii), [AuIII4O4(SeIVO3)4]4−

Yixian Xiang,Natalya V Izarova,Florian Schinle,Ulrich Kortz,Bineta Keita,Oliver Hampe

doi:10.1039/c2cc33795a

The selenite-capped polyoxo-4-aurate(iii), [AuIII4O4(SeIVO3)4]4−

Yixian Xiang, Natalya V Izarova + Show 4 more

https://doi.org/10.1039/c2cc33795a

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Journal: Chemical Communications	Publication Date: Jan 1, 2012
Citations: 35

Affiliation: Constructor University, Karlsruhe Institute of Technology, University of Paris-Sud, Laboratoire de Chimie Physique, Institut Polytechnique de Paris, French National Centre for Scientific Research

#Condensation In Aqueous Medium #Se NMR + Show 8 more

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Abstract

The discrete heteropolyaurate [Au(III)(4)O(4)(Se(IV)O(3))(4)](4-) (Au(4)Se(4)) represents only the second member of this class ever reported, and was synthesized via one-pot room temperature condensation in aqueous medium. was structurally characterized in the solid state and in solution by single-crystal XRD, TGA, FT-IR, (77)Se NMR, mass spectrometry and electrochemistry.

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