The Selective Transport of Ions in Charged Nanopore with Combined Multi-Physics Fields.

Pengfei Ma,Danting Zhao,Wenjie Zhang,Liuxuan Cao,Lingxin Lin,Zijing Huang,Zeyuan Zhao,Gonghao Lu,Jianxiang Zheng

doi:10.3390/ma14227012

Pengfei Ma, Danting Zhao + Show 7 more

Open Access

https://doi.org/10.3390/ma14227012

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Abstract

The selective transport of ions in nanopores attracts broad interest due to their potential applications in chemical separation, ion filtration, seawater desalination, and energy conversion. The ion selectivity based on the ion dehydration and steric hindrance is still limited by the very similar diameter between different hydrated ions. The selectivity can only separate specific ion species, lacking a general separation effect. Herein, we report the highly ionic selective transport in charged nanopore through the combination of hydraulic pressure and electric field. Based on the coupled Poisson–Nernst–Planck (PNP) and Navier–Stokes (NS) equations, the calculation results suggest that the coupling of hydraulic pressure and electric field can significantly enhance the ion selectivity compared to the results under the single driven force of hydraulic pressure or electric field. Different from the material-property-based ion selective transport, this method endows the general separation effect between different kinds of ions. Through the appropriate combination of hydraulic pressure and electric field, an extremely high selectivity ratio can be achieved. Further in-depth analysis reveals the influence of nanopore diameter, surface charge density and ionic strength on the selectivity ratio. These findings provide a potential route for high-performance ionic selective transport and separation in nanofluidic systems.

Highlights

Nanoporous membranes attract broad interest due to their unique mass transport property and potential applications in DNA sequencing [1,2], molecular separation [3,4], chemical sensing [5,6], ion filtration [7], seawater desalination [8,9], and energy conversion [10,11]
The extraordinary property stems from the surface of the nanopore which provides exceptional interaction compared to the counterpart of the macro scale [12,13,14]. It leads to the selective transport of ions, which is similar to the biological ion channel across the cell membrane
This selective transport stems from the polarization effect near the pore entrance and the physical and chemical properties of the surface, resulting in anomalous ion selectivity, ionic conductance enhancement, and ionic current rectification [15,16,17]

Summary

Introduction

Nanoporous membranes attract broad interest due to their unique mass transport property and potential applications in DNA sequencing [1,2], molecular separation [3,4], chemical sensing [5,6], ion filtration [7], seawater desalination [8,9], and energy conversion [10,11]. The extraordinary property stems from the surface of the nanopore which provides exceptional interaction compared to the counterpart of the macro scale [12,13,14] It leads to the selective transport of ions, which is similar to the biological ion channel across the cell membrane. Driven by the hydraulic pressure, the ionic currents between different ions are distinct [36,37] These experimental phenomena implied that the highly selective ion transport may be achieved under the synergy of multi-physics fields in the nanopores. Further in-depth theoretical analysis reveals the influence of nanopore diameter, surface charge density and ionic strength on the selectivity ratio These findings provide a potential route for the general strategy of the ionic selective transport and the inspiration for the design of high-performance nanofluidic systems

Numerical Calculation

Models Parameters

Results and Discussion