The second and third order non-linear optical properties of liquid crystalline polymers

Abstract

Abstract The second and third order non-linear optical susceptibilities of several donoracceptor substituted side chain polymers, some of which exhibit mesophases, will be reported. The susceptibilities were measured by harmonic generation from thin films, typically 0·5 μm thick, at a fundamental wavelength of 1064 nm and 1579 nm. For second harmonic generation, the spin coated films were contact poled on a glass substrate with an interdigited electrode pattern. Typical values obtained were χ(2) 31 = 1 × 10−9 esu and χ(2) 33 = 3 × 10−9 esu, the largest value was χ(2) 33 = 6·3 × 10−9 esu. The difficulty in deriving reliable second order structure-property relations because of the large effect which the contact poling process has on the non-linear optical susceptibility of the films will be highlighted. The highest χ(3) value of 5·8 × 10−12 esu obtained from an amorphous film of a polymer with an asymmetrically substituted azo side group is comparable with the susceptibility of more typical third order non-linear materials such as the main chain polymers polyphenylacetylene and poly-p-phenylenebenzobisthiazole.