The Search for Efficient True Blue and Deep Blue Emitters: An Overview of Platinum Carbene Acetylide Complexes.

Abstract

Despite significant strides achieved in organic light emitting diode (OLED) based display technologies during the last decade, the search for highly stable and efficient true blue/deep blue emitters continues to remain elusive. During the past decade, emitters with the basic molecular scaffold consisting of Pt(II) acetylides and N-heterocyclic carbene (NHC) ligands have opened interesting opportunities to tune the emission properties with desired chromaticity in the blue and deep blue region. With an aim to achieve the desired CIE coordinates along with low device roll-off efficiencies and satisfactory color purity, a number of variations on the basic molecular fragment have been made. A number of NHC Pt(II) alkyne complexes bearing monodentate, bidentate and tridentate ligands have been synthesized and their photophysical investigations have been reported. Although NHC Pt(II) alkyne complexes have been explored in other areas of applications, much of the investigations have been primarily focused for their interesting emission properties appearing particularly in the shorter wavelength (450-495 nm) part of the electromagnetic spectrum for organic light emitting diode (OLED) devices. In this review, we provide an overview of the investigated NHC Pt(II) acetylide complexes by detailing their synthesis, luminescence properties, performance in devices and future perspectives.