Abstract
The rotational spectrum of bromoacetyl chloride, BrCH 2COCl, has been assigned using a pulsed molecular beam Fourier transform microwave spectrometer. It has been possible to determine the rotational and quartic centrifugal distortion constants of the energetically favoured conformer (anti-periplanar) as well as the complete bromine and chlorine quadrupole coupling tensors including their off diagonal elements for the following isotopomers: 79BrCH 2CO 35Cl, 81BrCH 2CO 35Cl, 79BrCH 2CO 37Cl, and 81BrCH 2CO 37Cl. Experimental results are supported by quantum chemical calculations.
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