Abstract
Ground-state rotational constants, centrifugal distortion constants and Cl nuclear quadrupole coupling constants were determined from the rotational spectra of two isotopomers (allene⋯ 35ClF and allene⋯ 37ClF) of a pre-reactive complex of allene and chlorine monofluoride. Chemical reaction between the components was avoided by using a fast-mixing nozzle in a Fourier transform microwave spectrometer. It is concluded that the observed complex is of the weakly bound, Mulliken outer type in which the Cl of ClF interacts with the π-bond of allene to give an L-shaped geometry with the heavy atoms coplanar.
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