Abstract

The pure rotational spectrum of deuterium isocyanide (DNC) was recorded in the frequency range from approximately 680 to 1985 GHz. Twenty-one new transitions in the vibrational ground and first excited bending states (01 e,f 0) have been assigned, namely R-branch transitions from J=9←8 to 25←24. In a least squares analysis of these new transition frequencies together with previously reported millimeter-wave data, spectroscopic parameters up to sextic order could be derived with high precision for both states. Furthermore, the ℓ-type doubling constant q and its centrifugal distortion terms q J and q JJ were obtained for the first excited bending state.

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