Abstract
Pure rotational spectra of the 79Br and 81Br isotopic species of gaseous hypobromous acid, HOBr and DOBr, as well the v 3 = 1 excited state of HOBr have been observed and analyzed. Structural parameters have been derived from the ground state rotational constants. The permanent molecular dipole moment of DOBr and the bromine nuclear quadrupole coupling and spin rotation constants of all the species have been determined.
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