Abstract
The five new vibrational bands in the range 5050-5200 Å of the laser induced fluorescence excitation spectra of NO2 were measured and rotationally assigned at room temperature. Though the spectra were rather congested, we can determine the band origins, and rotational and spin-rotation constants for these bands. All rotational structures analyzed are of the parallel type. It was shown that the electronic excited state Ã2B2 were heavily perturbed by the high lying vibration levels of ground state [Xtilde] 2 A 1 and that the interactions between these two electronic states was the main rationale for the complexity of NO2 visible spectra.
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