Abstract
The effects of water vapor and CO on the photooxidation of propylene in the presence of NOx, were investigated. The presence of up to 11 000 ppm of water vapor had no significant effect on either the consumption of hydrocarbon and NO, or the formation of N02 and 03. A simplified mechanism for the phooxidation of propylene accounts for the observation by showing that the concentration of the major reactive radical-the OH radical-is not affected by the presence of HN02 formed initially as a result of the presence of water.
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