Abstract
The relaxation kinetics of N 2O and CO 2 vibrationally excited molecules (VEM) in two-phase gas-cluster systems was investigated under conditions of supersonic expansion with condensation. The catalytic effect of clusters on the vibrational relaxation rate was revealed. The relaxation rate of clustered VEM, R c, and the probability of relaxation of VEM per collision with a cluster, P , as functions of the average number of molecules in a cluster, N , were obtained. Values of R c and P increase rapidly with increasing N , and at N = constant they decrease with decreasing cluster temperature.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
