Abstract

Abstract Suspended particulate matter has been studied in two Adriatic river mouths to assess its role as a transport vehicle for waste disposal into the Adriatic sea. The larger of the two, the Adige River (northwestern Adriatic coast, Italy), carries large quantities of solids and builds up a prodelta. the Krka River (eastern Adriatic coast, Croatia, Yugoslavia) is a typical karst river, and carries small quantities of suspended matter, since it drains carbonate terrains. The resulting disposal of contaminants into the Adriatic sea is largely governed by the adsorption/desorption processes occurring in the estuarine mixing region. Surface adsorption properties, the specific surface area, and the nature and reactivity of the organic film coating determine the partitioning of pollutants between the dissolved and particulate state. The observations reported point to the key role of particulates in transport of pollutants from land to sea. the concept of the assimilative capacity of the estuarine area requires detailed scientific knowledge on the geochemical behaviour of particulates. In the Adige River mouth, lead, chromium, zinc, and nickel are accumulated in the prodelta sediments, and thus the loading of the sea with these metals is diminished, whereas in the Krka River estuary, desorption and mobilization of some trace metals occurs.

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