Abstract

The theory of the reversible charge transfer (RCT) for infinite Euclidean three-dimensional space has been extended to include regular d-dimensional solids, where d=1,2,3. The space dimension determines the character of charge transfer kinetics. The back charge transfer's effect depends on the space averaging procedure. Comparison of two space averaging procedures shows the different kinetic behavior in the RCT process in three-dimensional Euclidean space. This difference is diminished with the decrease of the space dimension. We explain this fact by increase of the donor's excited state probability N(t) in low-dimensional space. This function distorts the behavior of the charge transfer kinetics in three-dimensional space. The charge separation increased with space dimension's growth.

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