Abstract

Polypropylene/polylactic acid (PP/PLA) blend (10–40% of PLA) and PP/PLA/MWCNTs nanocomposites (0.5, 1, and 2 wt% of MWCNTs) were prepared via melt compounding. Scanning electron microscopy revealed a co-continuous PLA phase in the PP/PLA blends with high PLA content. Moreover, the addition of 2 wt% multi-walled carbon nanotubes (MWCNTs) increased the tensile modulus and tensile strength of the PP/PLA40% by 60% and 95%, respectively. A conductive network was found with the addition of 2 wt% MWCNTs, where the electrical conductivity of the PP/PLA increased by nine orders of magnitude. At 2 wt% MWCNTs, a solid network within the composite was characterized by rheological assessment, where the composite turned from nonterminal to terminal behavior. Soil burial testing of the PP/PLA blend within 30 days in natural humus compost soil featured suitable biodegradation, which indicates the PP/PLA blend is as an appropriate candidate for food packing applications.

Highlights

  • Since the last decades, polymer blends and composites have been used in different applications due to their significant electrical, mechanical, the rmal, and biodegradation properties

  • The multi-walled carbon nanotubes (MWCNTs), PP, and polylactic acid (PLA) materials were dried for 24 h at 70 ◦C in an oven to remove the residue of humidity before the compounding

  • The morphology of the PP/PLA blends and PP/PLA/MWCNTs nanocomposites were studied by a field emission scanning electron microscope (FE-SEM) (TESCAN, model MIRA3, Czech Republic)

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Summary

Introduction

Polymer blends and composites have been used in different applications due to their significant electrical, mechanical, the rmal, and biodegradation properties. From the mechanical point of view, PLA behaves as a glassy polymer with high brittleness [21,22], featuring a tensile strength of 30 to 50 MPa and a tensile modulus of 2 to 4 GPa. the elongation at break of PLA is roughly low, in the range of 1% to 10%, depending on its molecular weight, enantiomeric purity, and the degree of crystallinity. The chemical interaction between two immiscible polymers (PP and PLA) is studied by Fourier-transform infrared spectroscopy (FT-IR) Mechanical properties, such as the tensile strength and tensile modulus, are studied to evaluate the stiffness and elongation at break of the polymer blends and composites. The biodegradability of the blends is studied via the soil burial test

Materials
Material Compounding and Sample Preparation
Characterizations of Blends and Nanocomposites
Thermogravimetric Analysis
Mechanical Tests
Rheological Measurements
Electrical Properties
Blend Biodegradability
Characterization and Morphology
FT-IR Spectroscopy Analysis
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