Abstract

During the last 10 years, there has been a resurgence of interest in ordered alloys for structural uses due to the discovery of the dramatic ductilizing effect of boron on grain boundaries in Ni3Al. With this discovery, it was hoped that the property of an increase in strength as the temperature is increased could be utilized as well as the excellent oxidation resistance. Now, alloys based on Ni3Al are in use in specialized industrial applications, such as high temperature forging dies and being tested for use as turbocharger rotors. Due to the successful control of the grain boundary strength in Ni3Al, other systems were reexamined. For example, Fe3Al was also thought to have inherently brittle grain boundaries, however it was found that with purer alloys the material failed by cleavage. Subsequently, development of practical, inexpensive, oxidation resistant alloys has proceeded. Fe3Al alloys are currently being tested for automobile exhaust applications.

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