Abstract
The leachability of solid nuclear waste forms has been studied by many investigators to evaluate the short-term kinetics of elemental release or to determine the effects of leachant composition or other system parameters. Some general observations from these studies have included: incongruent leaching; formation of reaction layers that contain rare-earth, alkaline-earth, or transition metal elements; and apparent saturation of some elements in solution while others continue to be leached. Before these observations can be used to predict long-term performance of waste glasses under repository conditions, the mechanisms controlling the release of elements from the solid must be understood.
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