Abstract
When argon ion laser radiation is focused sharply on the surface of a substrate in a reactor, a hot spot is induced and a needle-like solid begins to grow along the direction of the laser beam. By comparing the phenomena observed during the laser pyrolysis of a series of compounds, Si(CH 3) x Cl 4−x ( x = 0 to 4), it is suggested that the initial process of the laser pyrolysis might be the combination of two hydrogen atoms of two methyl groups in the same or different molecules. Therefore, the number of the hydrogen atoms is important in this laser pyrolysis - the more hydrogen atoms the reactant has, the easier it can be pyrolyzed at the hot spot induced by the laser radiation.
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