Abstract

Advances in the development of ceramics and ceramic composites rely on an understanding of the mechanisms which contribute to the formation of desired microstructural features or control the mechanical response of the material. For example, in silicon nitride, careful control of the liquid phase composition and growth conditions permits the development of elongated grains which provide in-situ reinforcement of the material. Electron microscopy studies have aided in understanding the solution-reprecipitation process which controls the growth of silicon nitride as well as the role of the liquid phase on this process. The composition and thickness of the residual glass phase at the grain boundaries and triple points are important for both the toughening and creep response of the material and can only be realistically analyzed by high resolution analytical and electron imaging techniques.

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