Abstract
From the amount and nature of admixtures in nickel and zinc deposits obtained in the presence of surface-active substances containing sulphur, a conclusion is drawn about the leading rôle of the chemical nature of the metal in the determination of the type of its interaction with a surface-active addition agent. The insufficiency of a purely adsorptional mechanism in the estimation of the effect of such substances on the processes of electrocrystallization is pointed out. A relationship is established between the formation of “cryptocrystalline” structures of nickel deposits as well as their peculiar properties, and the chemical reaction in zone of the metal reduction.
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