Abstract
The present work has concentrated on the role of carbon in controlling the microstructure and strength of V-N structural steels containing 0.04-0.22%C. Carbon content has usually been considered not relevant to precipitation strengthening when the precipitation occurs in ferrite because of the very small carbon content in solution in ferrite at equilibrium. We demonstrate that the effective carbon for precipitation in ferrite is much greater than this during the period of phase transformation, which in turn has a great effect on precipitation strengthening. Such behaviour is explained on the basis that the activity of carbon in ferrite is abnormally high in the presence of under-cooled austenite and before cementite nucleation so that profuse nucleation of vanadium carbonitride is encouraged. This new mechanism for precipitation is particularly significant for medium carbon steels typically used for hot rolled bars and sections. The total carbon content of the steel also contributes to the yield strength by increasing the volume fraction of pearlite. It is shown that the contribution from pearlite may be stronger than generally recognised.
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