Abstract

The effect of annealing on EPMA spectra, infrared absorption spectra, optical gap (E o) and photoconductivity (Δσp) has been studied for a-Si:H films prepared both by ArSiH 4 glow discharge decomposition (GD) and ArH 2 reactive sputtering (SP) under various deposition conditions. SP films and GD-cathode films involve Ar atoms more than 5 at.% while GD-anode films less than 1 at.%, and Ar atoms are never evolved at least up to 400°C. It has been indicated that Ar atoms play the role of steric hindrance against not only H 2 effusion but also thermal rearrangement of H local environments, which is strongly correlated with differences in E o and Δσp between GP and SP films

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