Abstract

The activity for ammonia oxidation and the intermediates formed during the reaction have been studied on platinum, palladium, rhodium, ruthenium, iridium, copper, silver and gold electrodes. The activity in the selective oxidation to N 2 is related directly to the nature of the species at the surface: the electrode is active if NH ads (or NH 2,ads) is present and deactivates when N ads is present. The potential at which NH ads or N ads is formed is metal dependent. The observed trend in the strength of adsorption of N ads is Ru>Rh>Pd>Ir>Pt≫ Au, Ag, Cu. This trend corresponds well with the trend observed in the calculated heat of adsorption of atomic nitrogen, with iridium being an exception. Platinum is the best catalyst for this reaction because N ads is formed at high potential, compared to rhodium and palladium, but seems to stabilize NH ads rather well. Gold, silver and copper do not form NH ads or N ads, and show only an activity when the surface becomes oxidized. The metal electrodissolution is enhanced by ammonia under these conditions. Most metals produce oxygen-containing products, like NO and N 2O, at potentials where the surface becomes oxidized.

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