Abstract

A number of blocks of resinous materials were found in the cargo of a 12th- to 13th-century shipwreck, discovered in the late 1980s in the Java Sea near the Indonesian islands of Sumatra and Java and excavated in 1996. These well-preserved blocks presumably were trade materials used for religious, medicinal, cosmetic, decorative or practical purposes. Such materials, derived from plants and termed exudates, generally include frankincense, myrrh, ‘gum benjamin’, liquidambar, dragon's blood, dammar, copal and amber. The source of the cargo resin could not be determined from the site. Investigation by nuclear magnetic resonance (NMR) spectroscopy has revealed that the molecular structure corresponds to that of modern resin from the plant family Dipterocarpaceae, known in trade as dammar and closely resembling Group B copal and amber. Other molecular classes of exudates are excluded. Such materials are not present in the Middle East, which then cannot be their source. The NMR spectra differ from those of Group B samples from Australia, Papua New Guinea and Indonesia, but resemble those from India or Japan. The spectra indicate that the saline environment had a similar effect on the molecular structure to heating and aging.

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