Abstract

Marine shale is extensive throughout the subsurface, and commercially well-developed as natural gas producers throughout south China, attracting attention in recent years by both politicians and scientists on a variety of issues. Previous research on shale has predominantly focused on the Longmaxi and Niutitang Formations in the Sichuan Basin, but rarely on the periphery in northwestern Hunan Province where the Niutitang Formation has long been known as a potential shale gas reservoir. In this study, hydrocarbon generation potential, reserving performance, and shale gas potential of the Niutitang Formation from northwestern Hunan Province was studied to determine its gas producing potential. Total organic carbon (TOC) analysis, rock-eval pyrolysis, vitrinite reflectance and organic maceral analysis, mercury intrusion, nitrogen adsorption, and methane adsorption were run on a total of 52 samples from the SY well consisting of the Upper and Lower Members of the Niutitang Formation. Analysis of the results showed that the Niutitang shale has high TOC content (2.37% on average), high thermal maturity (3.15% on average), and oil-prone kerogen types, indicating good shale gas potential in the study area. The shale consists of relatively high concentrations of brittle minerals (quartz and feldspar, 69% on average) and low clay content (22% on average), indicating a brittle shale. The shale is a tight formation, with measured porosity averaging 2.66% (free gas potential) and methane adsorption capacity averaged 1.55 cm3/g (adsorbed gas potential). TOC and burial depth control reservoir space of the shale. The Lower Member samples had lower porosity but higher methane adsorption capacity than those from the Upper Member, indicating that a relatively larger amount of gas may occur as adsorbed gas in the Lower Member. It is suggested that the Lower Member of the Niutitang Formation is the ideal location for exploration and development of shale gas due to consistently thick organic-rich layers, high TOC content, high brittleness index, and stronger adsorption capacity.

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