The repulsive Coulomb barrier along a dissociation path of the BeC(2-)(4) dianion.

Abstract

We present ab initio calculations of the repulsive Coulomb barrier for several geometrically stable isomers of the BeC(2-)(4) dianion. We describe how the deformation of certain isomers can account for the experimental Coulomb explosion images of the dianion. For the most stable linear isomer, C(-)(2)BeC(-)(2), we examined the electron tunneling process along the dissociation path to obtain C(-)(2) plus BeC(-)(2). We found the crossing point for autodetachment to be R(c)(dis)= 3.25 A. R(dis) is the bond length between C(-)(2) and BeC(-)(2); at this point, the electron tunneling energy is equal to the maximum of the repulsive Coulomb barrier. In the framework of the Wenzel-Kramer-Brioullin theory, the electron-loss lifetime of the metastable C(-)(2)BeC(-)(2) dianion at the equilibrium geometry, R(dis) = 1.64 A, was estimated to be about 5 ms. This lower limit is in agreement with the experimental results in which the BeC(2-)(4) dianion has a lifetime much longer than 5 micros.