Abstract

AbstractThe continuous removal of heavy metals by the biological solids in an anaerobic reactor has been examined. The metals used were chromium (III), zinc and lead. Both competitive and non‐competitive removal was studied. The results were evaluated in terms of adsorption isotherms and were compared with earlier batch studies. This suggested that the sludge acted as a cation‐exchange material, with chromium having a much lower binding intensity than lead and zinc. The data also suggest that the nature of the sludge surface is of considerable significance in determining the capacity and intensity of binding. The effect of the metals on biogas formation was also examined. This showed that inhibition of the gas formation was a function of the metal concentration and that the relative toxicities appeared to be zinc > lead > chromium.

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