The remediation efficiency of heavy metal pollutants in water by industrial red mud particle waste

Abstract

This study aims to treat heavy metal pollutants in water by applying red mud particle waste. An experiment on the static adsorption of heavy metal ions Pb 2 + (or Cd 2 + and Cu 2 + ) by red mud particles was carried out, and the influences of the type of heavy metal ion, ion concentration, pH value, red mud dosage, reaction time, and temperature on adsorption performance were explored. The competitive adsorption mechanisms of various coexisting heavy metal ions by red mud particles were compared. The red mud samples loaded and not loaded with heavy metal ions were detected by zeta potential measurement, scanning electron microscopy, and Fourier transform infrared spectrometry. The adsorption strength of red mud particles for heavy metal ions was ranked in the sequence of Pb 2 + , Cd 2 + , and Cu 2 + , while increasing temperature enhanced their adsorption. When the initial pH values were 4.3, 5.0, and 3.6 for Pb 2 + , Cd 2 + , and Cu 2 + solutions, the removal peaks were 94.5%, 92.8%, and 78.1%, respectively. The preferred order of adsorption for red mud was Pb 2 + , Cd 2 + and then Cu 2 + under the competitive mechanism of binary/ternary systems due to the discrepancy in the functional groups of red mud particles loaded with different heavy metal ions. • A concept for purifying heavy metal pollutants in water using red mud is proposed. • The competitive adsorption mechanism of various heavy metal ions is revealed. • The influence of temperature on the interaction of heavy metal ions and red mud is emphasized. • An adsorption–desorption model with hysteresis is verified by experimental results.