Abstract
Relative permittivities (є) and the excess property (єE) for the binary mixtures formed by 1,2-dimethoxyethane with water have been measured at various temperatures in the range from -10 to +80°C. These mixtures have interesting properties for electroanalytical applications. Their study should help in understanding the phenomenology of cosolvency towards ionizable and inert solutes. The results of the єE analysis are discussed in terms of the influence of interactions between the components, order and degree of packing in the mixtures, and any other structural effect which occurs in solution.
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