Abstract

Martin’s equation, Δ sln g G = Δ sln g G o + z δ sln g G , is extended to cover vaporization free energy ( Δ l g G ) . The extended equation is further expanded in terms of enthalpy and entropy and then used to correlate vaporization enthalpy ( Δ l g H ) and enthalpy of transfer from solution to gas ( Δ sln g H ) . Data available in the literatures are used to validate and support the speculations derived from the proposed equation.

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