Abstract
The rates of reduction by chromium(II) of Co(en)2(NH2CH2CO2)2+(carboxylate-bridged), Co(en)2(O2CCH2SMe)2+(carboxylate-bridged) and Co(en)2(NH2CH2SMe)3+(outer-sphere) indicate reactivity advantages for chelated bridging carboxylate and nonbridging cis thioether ligands in inner-sphere reactions and a high reactivity associated with thioether functions in outersphere reactions.
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