Abstract
Making use of the molecular closed-orbit theory and a new model potential for the Rydberg molecule, we calculated the recurrence spectra of HeH(+) molecule ion in a magnetic field for different quantum defects. The Fourier transformed spectra of HeH(+) molecule ion have allowed direct comparison between peaks in the spectra and the scaled action values of closed orbits of the excited electron in the external fields. We find that the spectral modulations can be analyzed in terms of the scattering of the excited electron on the molecular core. Unlike the case of the Rydberg atom where the elastic scattering is predominant, modulations produced by inelastic scattering are also vital to the photoabsorption spectrum of Rydberg molecule. Our results are in good agreement with the quantum results, which suggest that our method is correct.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
