Abstract
The reactivity of germylene and stannylene based on 9,10-phenanthrenediimine are described. Complexes of nickel and iron carbonyls with a coordinated germylene were obtained in good yields under mild conditions. The abilities of germylene to be involved in oxidative addition reactions with preserving of N-heterocycle were demonstrated in reactions with dithio-bis(tricarbonyliron) and elemental sulfur. All the compounds were characterized structurally by X-ray diffraction analysis.
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