Abstract

The reaction of the anionic gallium(I) N-heterocyclic carbene (NHC) analogue 3 with the solution stable digermene 5 results in the formation of the gallium NHC – germylene complex 8. The gallium NHC – germylene complex 8 was derivatized with CH3I and (CH3)3SiCl.Key words: digermene, carbene analogue, germylene, gallium(I).

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