Abstract
The reactivity of a nucleophilic nickel acylate complex with a tungsten carbene complex, Fe(CO) 5, Cr(CO) 6, PPh 3, and CO was investigated. With the tungsten carbene complex, a methyl transfer occurred. With the metal carbonyl complexes, the acylate group on the nickel and a carbonyl on the iron or chromium traded places. With the PPh 3 and CO, the acylate anion was replaced by the phosphine or CO ligand.
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