Abstract
Phosphine functionalized imidazolium precursors were reacted with triiron(0)- resp. triruthenium(0)dodecacarbonyl in order to compare the reactivity of the Group VIII metals. Furthermore, [(η6-cymene)RuCl2]2 was treated in a transmetallation reaction with the silver(I) resp. copper(I) complexes of the corresponding imidazolylidenes possessing sterically largely different substituents at the NHC site, in order to evaluate the influence of these substituents on the catalytic activity of the ruthenium complexes.
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