Abstract
Abstract The structure of the product of the interaction of dichlorides of allenylphosphonic acids with sulfenyl chlorides depends on the nature of sulfenyl chlorides and substituents at the terminal carbon atom of allenic system. Arylsulfenyl chlorides and dichlorides of γ,γ-dialkylsubstituted allenylphosphonic acids form diene products. Phosphonesulfenyl chloride acts as chlorinating agent to form 4-chlorooxaphospholenes. The dichloride of propadienephosphonic acid reacts with phenylsulfenyl chloride yielding the addition product.
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