Abstract
Abstract A mechanistic study of a series of dinuclear complexes produced by the complexation of alkyne-containing bisphosphine ligands with Ir and Rh has been performed by experimental analysis as well as density functional theory (DFT) calculations. The key process is oxidative cyclization involving two metals and two alkyne-containing ligands 1. The related alkyne-bridged dimer 7, considered as an intermediate, was determined using X-ray measurements. The DFT calculation supported that the core metals alter the reorganization pathways from alkyne-bridged dimer, leading to the unique structures 4 and 5.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
