Abstract
Enynes having the 4-oxa-6-en-1-yne, 4-tosylaza-6-en-1-yne and 5-oxa-7-en-1-yne system, and 5,7-dioxa-1-octyne were reacted with triphenylstannylcobaloxime, which is a source of the triphenylstannyl radical and cobaloxime radical. The reaction pattern is different under photochemical and thermal conditions. Photochemical reaction gave the products formed by the addition of the triphenylstannyl radical to the acetylene group followed by the tandem addition of the intermediate vinyl radical to the intramolecular olefin. Thermal reaction gave triphenylstannyl-substitution products at the terminal position of the acetylene moiety. Thus, the photochemical reaction takes a free radical pathway, and the thermal reaction is proposed to take a single electron transfer mechanism.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have