Abstract
The kinetics of the reactions of the ion SH+ with CH4 and C2H2 and SiH+ with C2H2 and NH3 has been investigated using selected ion flow drift tube technique (SIFDT). The reaction rate coefficients and the products branching ratio have been determined as a functions of the reactant ion/reactant neutral average centre-of-mass kinetic energy (KECM=0.05–2eV). The studied reactions are fast at thermal and near thermal energies and have negative energy dependencies of the reaction rate coefficients.
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