Abstract
AbstractThe addition of sodium perfluoroalkanesulfinates (RFSO3Na) to various olefins (CH2=CHR) initiated by Fenton reagent (Fe2+‐H2O3) in the presence of sodium azide gave the adducts RFCH3‐CHN3R in good yield. A radical mechanism was proposed based on the EPR and other evidences. The adducts were readily reduced through catalytic hydrogenation to give the corresponding amines RFCH2CH(NH3)R in high yield. The reaction represents a convenient and effective route to these useful organofluorine compounds.
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