Abstract
Abstract A new method has been developed for the formation of a silicon-silicon bond. Hydrosilanes having at least one phenyl or one trimethylsilyl group on a silicon atom were subjected to reaction with chlorosilanes to give unsymmetrically substituted disilanes in the presence of secondary or tertiary Grignard reagent which was inert to both chlorosilanes and hydrosilanes. The method was extended to the preparation of benzyl, allyl, and alkylsilanes.
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