Abstract

- In the present work, novel phosphazene derivatives, monospiro- (1), dispiro- (2), and trispiro-2,2-bis(bromomethyl)-1,3-propandioxy (3) substituted cyclotriphosphazatrienes were synthesized with the reaction of bromoneopentyl glycol(2,2-bis(bromomethyl)-1,3 -propandiol) with hexachlorocyclotriphosphazatriene, N 3 P 3 Cl 6 . The structures of the compounds were determined by elemental analysis, mass spectrometry, 1 H and 31 P NMR spectroscopy. The thermal properties of the compounds (1), (2) and (3) were investigated by DSC and TGA.

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