Abstract
An equilateral Nb3 triangle the edges of which are spanned by a BS4 tetrahedron and bridged by sulfido ligands on the “underside” is found in cluster 1. The synthesis of this cluster with an unusual electron configuration shows that tetrathioborates can serve as ligands in organometallic chemistry. C = η5-EtMe4C5.
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More From: Angewandte Chemie International Edition in English
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